Anhydrite pseudomorphs and the origin of stratiform Cu–Co ores in the Katangan Copperbelt (Democratic Republic of Congo)   总被引：1，自引：1，他引：0  

Ph. Muchez  P. Vanderhaeghen  H. El Desouky  J. Schneider  A. Boyce  S. Dewaele  J. Cailteux 《Mineralium Deposita》2008,43(5):575-589

The stratiform Cu–Co ore mineralisation in the Katangan Copperbelt consists of dispersed sulphides and sulphides in nodules and lenses, which are often pseudomorphs after evaporites. Two types of pseudomorphs can be distinguished in the nodules and lenses. In type 1 examples, dolomite precipitated first and was subsequently replaced by Cu–Co sulphides and authigenic quartz, whereas in type 2 examples, authigenic quartz and Cu–Co sulphides precipitated prior to dolomite and are coarse-grained. The sulphur isotopic composition of the copper–cobalt sulphides in the type 1 pseudomorphs is between −10.3 and 3.1‰ relative to the Vienna Canyon Diablo Troilite, indicating that the sulphide component was derived from bacterial sulphate reduction (BSR). The generation of during this process caused the precipitation and replacement of anhydrite by dolomite. A second product of BSR is the generation of H₂S, resulting in the precipitation of Cu–Co sulphides from the mineralising fluids. Initial sulphide precipitation occurred along the rim of the pseudomorphs and continued towards the core. Precipitation of authigenic quartz was most likely induced by a pH decrease during sulphide precipitation. Fluid inclusion data from quartz indicate the presence of a high-salinity (8–18 eq. wt.% NaCl) fluid, possibly derived from evaporated seawater which migrated through the deep subsurface. ⁸⁷Sr/⁸⁶Sr ratios of dolomite in type 1 nodules range between 0.71012 and 0.73576, significantly more radiogenic than the strontium isotopic composition of Neoproterozoic marine carbonates (⁸⁷Sr/⁸⁶Sr = 0.7056–0.7087). This suggests intense interaction with siliciclastic sedimentary rocks and/or the granitic basement. The low carbon isotopic composition of the dolomite in the pseudomorphs (−7.02 and −9.93‰ relative to the Vienna Pee Dee Belemnite, V-PDB) compared to the host rock dolomite (−4.90 and +1.31‰ V-PDB) resulted from the oxidation of organic matter during BSR.  相似文献   

The sandstone-hosted stratiform copper mineralization at Mwitapile and its relation to the mineralization at Lufukwe, Lufilian foreland, Democratic Republic of Congo   总被引：2，自引：0，他引：2  

Hamdy A. El Desouky  Philippe Muchez  Roger Tyler 《Ore Geology Reviews》2008,34(4):561-579

The Lufilian foreland is a triangular-shaped area located in the SE of the Democratic Republic of Congo and to the NE of the Lufilian arc, which hosts the well-known Central African Copperbelt. The Lufilian foreland recently became an interesting area with several vein-type (e.g., Dikulushi) and stratiform (e.g., Lufukwe and Mwitapile) copper occurrences. The Lufilian foreland stratiform Cu mineralization is, to date, observed in sandstone rock units belonging to the Nguba and Kundelungu Groups (Katanga Supergroup).The Mwitapile sandstone-hosted stratiform Cu prospect is located in the north eastern part of the Lufilian foreland. The host rock for the Cu mineralization is the Sonta Sandstone of the Ngule Subgroup (Kundelungu Group). A combined remote sensing, petrographic and fluid inclusion microthermometric analysis was performed at Mwitapile and compared with similar analysis previously carried out at Lufukwe to present a metallogenic model for the Mwitapile- and Lufukwe-type stratiform copper deposits. Interpretation of ETM+ satellite images for the Mwitapile prospect and the surrounding areas indicate the absence of NE–SW or ENE–WSW faults, similar to those observed controlling the mineralization at Lufukwe. Faults with these orientations are, however, present to the NW, W, SW and E of the Mwitapile prospect. At Mwitapile, the Sonta Sandstone host rock is intensely compacted, arkosic to calcareous with high silica cementation (first generation of authigenic quartz overgrowths). In the Sonta Sandstone, feldspar and calcite are present in disseminated, banded and nodular forms. Intense dissolution of these minerals caused the presence of disseminated rectangular, pipe-like and nodular dissolution cavities. Sulfide mineralization is mainly concentrated in these cavities. The hypogene sulfide minerals consist of two generations of pyrite, chalcopyrite, bornite and chalcocite, separated by a second generation of authigenic quartz overgrowth. The hypogene sulfide minerals are replaced by supergene digenite and covellite. Fluid inclusion microthermometry on the first authigenic quartz phase indicates silica precipitation from an H₂O–NaCl–CaCl₂ fluid with a minimum temperature between 111 and 182 °C and a salinity between 22.0 and 25.5 wt.% CaCl₂ equiv. Microthermometry on the second authigenic quartz overgrowths and in secondary trails related to the mineralization indicate that the mineralizing fluid is characterized by variable temperatures (Th = 120 to 280 °C) and salinities (2.4 to 19.8 wt.% NaCl equiv.) and by a general trend of increasing temperatures with increasing salinities.Comparison between Mwitapile and Lufukwe indicates that the stratiform Cu mineralization in the two deposits is controlled by similar sedimentary, diagenetic and structural factors and likely formed from a similar mineralizing fluid. A post-orogenic timing is proposed for the mineralization in both deposits. The main mineralization controlling factors are grain size, clay and pyrobitumen content, the amount and degree of feldspar and/or calcite dissolution and the presence of NE–SW to ENE–WSW faults. The data support a post-orogenic fluid-mixing model for the Mwitapile- and Lufukwe-type sandstone-hosted stratiform Cu deposits, in which the mineralization is related to the mixing between a Cu-rich hydrothermal fluid, with a temperature up to 280 °C and a maximum salinity of 19.8 wt.% NaCl equiv., with a colder low salinity reducing fluid present in the sandstone host rock. The mineralizing fluid likely migrated upwards to the sandstone source rocks along NE–SW to ENE–WSW orientated faults. At Lufukwe, the highest copper grades at surface outcrops and boreholes were found along and near to these faults. At Mwitapile, where such faults are 2 to 3 km away, the Cu grades are much lower than at Lufukwe. Copper precipitation was possibly promoted by reduction from pre-existing hydrocarbons and non-copper sulfides and by the decrease in fluid salinity and temperature during mixing. Based on this research, new Cu prospects were proposed at Lufukwe and Mwitapile and a set of recommendations for further Cu exploration in the Lufilian foreland is presented.  相似文献   

城区水文循环机制与改善策略分析          下载免费PDF全文

廖朝轩  詹丽梅  陈家梁  邱奕儒 《水科学进展》2008,19(1):49-53

在城区化过程中,由于人口快速成长且集中,随之而来的建筑物、道路等不透水面密度增加,导致地下水补给减少及破坏水文循环。为了解土地利用方式改变对长期水文量影响,建立一个适宜的城区水循环模式是非常重要的。选定台湾台北的六馆抽水站集水区进行分析,模式参数经过敏感度分析、率定与验证。采用改变不同透水铺面设置比例的方案,评估其对径流量、入渗量、蒸发散量的改变。并分析设置不同比例屋顶雨水贮集系统对地表径流量及供水量的改变。所建立的城区水循环模式是评估土地利用改变造成水文量的改变的一个有效工具,并可提供决策者做为城区土地利用决策的参考。  相似文献   

临涣矿区界沟煤矿工程地质条件研究     

黄芳友  张文永  徐胜平 《中国煤炭地质》2008,(7):55-58

根据主采煤层顶底板岩体岩性类型及结构面发育程度对其稳定性进行了评价：72煤层顶板以中等稳定一不稳定类型为主,82煤层顶板以中等稳定类型为主,10煤层顶板以中等稳定一稳定类型为主。在大量统计见煤点硬质岩百分含量（k值）的基础上,结合顶板岩石的单轴抗压强度,对各主采煤层顶底板工程地质类型进行了划分：72煤层以一、二类顶板为主,82、10煤层均以五类顶板为主。综合评价该矿工程地质条件为中等即Ⅲ类二型。根据研究成果,指出该矿在采掘过程中可能出现的工程地质问题,并依此提出了治理建议。  相似文献   

三维地震技术在煤层顶板稳定性研究中的应用     

孙立新  许崇宝  王真 《中国煤炭地质》2008,(11):55-57

龙固井田为全隐蔽的华北型煤田,位于巨野煤田中部,其首采扩大区主采煤层为3号煤层。考虑3煤层顶板稳定性主要受其顶板的构造信息和岩性信息影响,因此首先依据三维地震勘探综合解释成果及波阻抗反演解释成果对二者进行定量化,然后对波阻抗数据进行归一化处理,使得波阻抗数据和量化后的构造数据具有相同的变化范围及等量贡献。在此距离范围内构造和岩性的权值各为0．5,依此生成综合因素煤层顶板稳定性隶属度。分析3煤层顶板以上10m、20m处的综合因素煤层顶板稳定性隶属度图可以发现,该区3煤层顶板稳定性比较好。且其稳定性主要是受构造因素控制,岩性因素相对影响较小。  相似文献   

高产高效综放工作面顶板水综合防治   总被引：1，自引：0，他引：1  

付成祥  王兵虎冯玉 《中国煤田地质》2004,16(Z1):45-47

通 过 对 T2195工 作 面 顶板 涌 水 水 质化 验 、周 边 开 采 情 况 的 综 合 分 析 认 为:T2195工 作 面 涌 水 以 5煤 层 顶 板 水为 主,地面 注 浆水 只是 起 了间 接补 给 作用 。为 此提 出 继续 进行 地 面注 浆、进一 步 完善 井下 排 水系 统等 有 针对 性的 防 治水 措施 ,确 保 工作 面的 高 产高 效。  相似文献   

Chemistry and Sulfur Isotopes in a Chert-dominant Sequence around the Stratiform Manganese Deposit of the Noda-Tamagawa Mine, Northern Kitakami Terrane, Northeast Japan: Implication for Paleoceanographic Environmental Setting     

Kosei Komuro    Katsuyuki Yamaguchi  Yoshimichi Kajiwara 《Resource Geology》2005,55(4):337-351

Abstract. Chemistry and sulfur isotopes are analyzed for a series of rocks in the chert‐dominant sequence around the stratiform manganese ore deposit of the Noda‐Tamagawa mine in the northern Kitakami Terrane, northeast Japan. The sequence is litholog‐ically classified into six units in ascending order: lower bedded chert, lower black shale, massive chert, manganese ore, upper black shale, and upper bedded chert. The rocks around the manganese ore deposit exhibit anomalous enrichment in Ni (max. 337 ppm), Zn (102) and U (30) in the upper part of lower bedded chert, Mo (122), Tl (79) and Pb (33) in the lower black shale, MnO, Cu (786) and Co (62) in the manganese ore, and As (247) and Sb (17) in the upper black shale. The aluminum‐normalized profiles reveal zonal enrichment of redox‐sensitive elements around the manganese bed: Zn‐Ni‐Fe‐Mo‐U(‐Co), Tl‐Pb(‐Mo), Mn‐Fe‐Cu‐V‐Cr‐Co(‐Zn) and As‐Sb in ascending order. The uppermost part of the lower bedded chert and black shale exhibit negative Ce/Ce* values, whereas the massive chert, manganese ore and lower part of the upper bedded chert display positive values. The isotopic δ³⁴S values are 0±6 % in the lower part of the lower bedded chert, ‐19 to ‐42 % in the upper part of the lower bedded chert, ‐36 to ‐42 % in the lower black shale, ‐28 to ‐35 % in the massive chert, manganese ore and upper black shale, and ‐23±5 % in the upper bedded chert. Thus, there is a marked negative shift in δ³⁴S values in the lower bedded chert, and an upward‐increasing trend in δ³⁴S through the manganese ore horizon. The present data provide evidence for a change in the paleoceanographic environmental resulting from inflow of oxic deepwater into the stagnant anoxic ocean floor below the manganese ore horizon. This event is likely to have triggered the precipitation of manganese oxyhydroxides. The redistribution of redox‐sensitive elements through the formation of metalliferous black shale and manganese carbonate ore may have occurred in association with bacterial decomposition of organic matter during early diagenesis of initial manganese oxyhydroxides.  相似文献   

Chemical Profiles across a Jurassic Stratiform Manganese Deposit at Katsuyama in the Mino Terrane of Central Japan: Implications for Depositional Environment, Diagenetic Metal Redistribution and Paleoceanography     

Kosei Komuro  Koji Wakita 《Resource Geology》2005,55(4):321-336

Abstract. Inorganic chemical compositions are determined for a series of rocks crossing an Early Jurassic stratiform manganese ore deposit in a chert‐dominant sequence at Katsuyama, in the Mino Terrane of central Japan. The lithology in the vicinity of the manganese ore bed is classified into lower bedded chert, black shale, massive chert, manganese ore and upper bedded chert, in ascending order. The rocks surrounding the manganese deposit are anomalously high in certain elements: Pb (max. 29 ppm), Ni (1140) and Co (336) in the lower bedded chert, Mo (438), As (149), Tl (29) and U (12) in the black shales, V (210) and Cr (87) in the massive chert, and MnO and W (24) in the manganese ore. The aluminum‐normalized profiles reveal a distinct zonation of redox‐sensitive elements: Pb‐Zn, Ni‐Co‐Cu(‐Zn) and U‐Cr in the lower bedded chert, Mo‐As‐Tl in the black shale, V(‐Cr) in the massive chert, and Mn‐Fe‐Ba‐W in the manganese ore, in ascending order. The lower and upper bedded cherts and manganese ore generally exhibit flat rare earth element patterns with positive Ce anomalies, whereas the uppermost part of the lower bedded chert, the black shale and massive chert have flat patterns with weak or nonexistent negative Ce anomalies and weak positive Eu anomalies. The strong enrichment in Ni, Co, W, Tl and As detected in the Katsuyama section is not recognized in other sediments, including those of anoxic deposition origin, but is identified in modern ferromanganese nodules, suggesting that metal enrichment in the Katsuyama section is essentially due to the formation of ferromanganese nodules rather than to deposition in an anoxic environment. The observed elemental zonation is well explained by equilibrium calculations, reflecting early diagenetic formation and associated gradual reduction with depth. The concentration profiles in combination with litho‐ and biostratigraphical features suggest that formation of these bedded manganese deposits was triggered by an influx of warm, saline and oxic water into a stagnant deep ocean floor basin in Panthalassa at the end of the middle Early Jurassic. Paleoceanographic environmental controls thus appear to be important factors in the formation and preservation of this type of stratiform manganese deposit.  相似文献   

Experimental study on the hydrological performance of green roofs in the application of novel biochar     

Shan Huang  Ankit Garg  Guoxiong Mei  Disheng Huang  Rahul Balaji Chandra  Shaji Gayathri Sadasiv 《水文研究》2020,34(23):4512-4525

Biochar has the potential to be a soil amendment in green roofs owing to its water retention, nutrient supply, and carbon sequestration application. The combined effects of biochar and vegetated soil on hydraulic performance (e.g., saturated hydraulic conductivity, retention and detention, and runoff delay) are the crucial factor for the application of the novel biochar in green roofs. Recent studies investigated soil water potential (i.e., suction) either on vegetated soil or on biochar-amended soil but rarely focused on their integrated application. With the purpose of investigating the hydraulic performance of green roofs in the application of biochar, the combined effect of biochar and vegetated soil on hydrological processes was explored. Artificial rainfall experiments were conducted on the four types of experimental soil columns, including natural soil, biochar-amended soil, vegetated natural soil, and vegetated biochar-amended soil. The surface ponding, bottom drainage and the volumetric water content were measured during the rainfall test. Simulation method by using HYDRUS-1D was adopted for estimating hydraulic parameters and developing modelling analysis. The results indicated that the saturated hydraulic conductivity of vegetated soil columns were higher than bare soil columns. The addition of biochar decreased the saturated hydraulic conductivity, and the magnitude of decrease was much significant in the case of vegetated soil. The influence of vegetation on permeability is more prominent than biochar. The vegetated biochar-amended soil has the highest retention and detention capacity, and shows a preferable runoff delay effect under heavy rain among the four soil columns. The results from the present study help to understand the hydrological processes in the green roof in the application of biochar, and imply that biochar can be an alternative soil amendment to improve the hydraulic performance.  相似文献   

不同类型冷却屋顶方案对城市群热环境的缓解效果     

张弥  马红云  林卉娇  李海俊  王莹 《气候变化研究进展》2021,17(1):45-57

利用耦合单层城市冠层模型的中尺度数值模式WRF/UCM,选取8组不同反照率和绿化比例的屋顶冷却方案进行敏感性试验,模拟研究不同冷却屋顶方案对长三角城市群2013年夏季城市热环境的影响,并分析其影响机制。结果表明：不同冷却屋顶方案对城市群热环境的缓解效果与屋顶参数之间呈很强的线性关系。高温热浪天气下,HR4（反照率为1.0）和GR4（屋顶绿化率为100%）方案的制冷度日数分别降低了14.7%和10.9%,节约的能源比普通夏日更多。同时,高温热浪天气会增强热岛强度,高反照率屋顶方案在白天对热岛起到更有效的缓解,热浪天气下日平均热岛强度最大可降低1.36℃。相同方案下,在高温热浪天气下的缓解效果均胜于普通夏日,平均而言,高反照率屋顶和屋顶绿化的降温效果分别增大38.5%和34.9%,增湿效果分别增大29.5%和21.9%,这主要是由于在高温热浪天气下,高反照率屋顶方案能够减少更多的净辐射通量,屋顶绿化方案能够释放更多的潜热通量。此外,城市格点密集区域的降温效果优于分散的城市区域,处于城市群中的常州区域较单独的杭州区域的降温幅度平均高32%。  相似文献